N-Ethyl-2-[1-(2-hydroxy-6-methoxyphenyl)ethylidene]hydrazinecarbothioamide
نویسندگان
چکیده
In the title compound, C(12)H(17)N(3)O(2)S, the dihedral angle between the mean planes of the hydrazinecarbothio-amide group and the benzene ring is 86.8 (4)°. In the crystal, inter-molecular O-H⋯S hydrogen bonds link the mol-ecules into chains along [001]. The crystal studied was an inversion twin, the refined ratio of the twin components being 0.98021 (3):0.01978 (7).
منابع مشابه
(2E)-2-[1-(2-Hydroxy-4-methoxyphenyl)ethylidene]-N-phenylhydrazinecarboxamide monohydrate
The title compound, C(16)H(17)N(3)O(3)·H(2)O, exists in the E conformation with respect to the azomethine C=N double bond. While the phenyl ring is almost coplanar with the central hydrazinecarboxamide group [dihedral angle = 14.18 (11)°], it is twisted slightly with respect to the other aromatic ring in the mol-ecule, with a dihedral angle of 22.88 (13)°. The packing is dominated by O-H⋯O, N-H...
متن کاملDibutyl{N′-[1-(5-chloro-2-oxidophenyl-κO)ethylidene]-3-hydroxy-2-naphthohydrazidato-κ2 N′,O 2}tin(IV)
The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bondi...
متن کاملAnilinium 3-(4-hydroxy-3-methoxyphenyl)prop-2-enoate
The structure of the title salt, C(6)H(8)N(+)·C(10)H(9)O(4) (-), is stabilized by N-H⋯O and O-H⋯O hydrogen bonding between 3-(4-hy-droxy-3-meth-oxy-phen-yl)prop-2-enoate anions and anilinium cations, which links the components into a two-dimensional array.
متن کامل2-[1-(2-Hydroxy-6-methoxyphenyl)ethylidene]-N-methylhydrazinecarbothioamide acetonitrile monosolvate
In the title compound, C11H15N3O2S·C2H3N, the dihedral angle between the benzene ring and the mean plane of the hydrazinecarbothio-amide group is 75.1 (2)°. In the crystal, the main mol-ecule is linked to the solvent mol-ecule by a weak N-H⋯N hydrogen bond while O-H⋯S hydrogen bonds link the mol-ecules into columns along [100].
متن کامل(Z)-N-Ethyl-2-(5-fluoro-2-oxoindolin-3-ylidene)hydrazinecarbothioamide
In the title compound, C(11)H(11)FN(4)OS, an intra-molecular N-H⋯O hydrogen bond generates an S(6) ring. In the crystal, mol-ecules form chains through N-H⋯O hydrogen bonds, which are extended by N-H⋯S hydrogen bonds into an infinite three-dimensional network.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012